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The Adventure Of A Lifetime band will perform at The O2's Indigo on Wednesday 24 February.
Coldplay have been confirmed for War Child's Passport To BRITs Week together with O2.
Chris Martin and co. have been added to the string of dates, which sees huge British acts playing intimate venues across London for a good cause.
The Adventure Of A Lifetime band will perform at The O2's Indigo on Wednesday 24 February - the same evening of The BRIT Awards.
The band said: "We’re delighted to play this special show for War Child to raise funds for their crucial work with children dealing with the aftermath of conflict."
Tickets will go on sale for £75 on 8 February.
Fans can also be entered into a draw for the chance to see their favourite artist at Passport to BRITs Week, by making a donation at www.warchild.org.uk/passport.
Donations are £4.50 per entry and the draw is open from 9am on Monday 8 February until 23.59pm on Friday 19 February.
The money raised will support War Child's vital work, providing protection to children whose lives are torn apart by conflict.
See the full line-up of gigs below:
15 February: Bloc Party, Bush Hall, London
16 February: Frank Turner, The Monarch, London
17 February: Professor Green, Oslo, London
21 February: Jamie xx, LN-CC, London
23 February: Above & Beyond, The Pickle Factory, London
23 February: Lianne La Havas, Sofar Sounds living room, London
24 February: Coldplay, Indigo At The O2, London*
26 February: Florence + The Machine, St John at Hackney